张松林，男，博士，教授，副院长，硕士生导师
个 人 简 介
教育经历
1999年9月进入中国科学技术大学应用化学系学习，2004年7月获得中国科学技术大学应用化学专业理学学士学位和计算机科学与技术专业工学学士双学位。同年9月保研到中国科学技术大学化学系硕博连读，并于2010年6月获得中国科学技术大学有机化学专业理学博士学位，导师郭庆祥教授。期间于2007年10月到2008年10月，在国家留学基金委资助下，在日本东京大学化学系作为访问学者联合培养一年，导师Eiichi Nakamura教授。
工作经历
2010年7月起至今，任职于江南大学化学与材料工程学院。2019年3月起至今，作为中央机关单位援疆干部人才在8040威尼斯化学工程学院挂职工作。
研 究 方 向
有机新反应发展、机理研究及在医药和材料中的应用，研究特色是实验研究结合理论计算的方法。研究取得了一些原创性的成果，在国际主流化学期刊包括J. Am. Chem. Soc., Org. Lett., Chem. Commun.等发表了40余篇高质量的SCI论文，部分论文多次被引用。
主 讲 课 程
研究生：《高等有机化学》
主持和参与科研项目
1.国家自然科学基金面上项目(21472068)；
2.国家自然科学基金青年项目(21202062)；
3.江苏省自然科学基金青年项目(BK2012108)；
4.中国博士后科学基金第52批面上资助项目(2012M520993)；
5.中央高校基本科研业务费；
6.其它一些企业横向项目。
主要科研成果
代表性论文
[1] Jia-Jia Dong and Song‐Lin Zhang*. Synthesis of 2,2,2‐Trifluoroethyl Oxazoles, Oxazolines and Furans via Alkyne Oxytrifluoromethylation, Advanced Synthesis & Catalysis, 2020, 362(4), 795-800.
[2] Song-Lin Zhang*, Chang Xiao, Hai-Xing Wan and Xiaoming Zhang*. General and selective syn-carboxylation-trifluoromethylation of terminal alkynes: application to the late-stage modification of dehydrocholic acid. Chem. Comm. 2019, 55(28), 4099-4102.
[3] Hao-Ran Zhang, Chang Xiao, Song-Lin Zhang* and Xiaoming Zhang*. Radical C−H Bond Trifluoromethylation of Alkenes by High‐Valent Copper(III) Trifluoromethyl Compounds. Adv. Synth. Catal. 2019, 361(23), 5305-5310.
[4] Song-Lin Zhang* and Jia-Jia Dong. Hydrogen-Bonding-Assisted α-F Elimination from Cu–CF3 for in Situ Generation of R3N·HF Reagents: Reaction Design and Applications. Org. Lett. 2019, 21(17), 6893–6896.
[5] Song-Lin Zhang* and Jia-Jia Dong. Mechanism and chemoselectivity origins of bioconjugation of cysteine with Au(III)-aryl reagents. Org. Biomol. Chem. 2019, 17(5), 1245-1253.
[6] Chang Xiao and Song-Lin Zhang*. Isolation of OH-bridged Ag(I)/Cu(III) and ion-pair Cu(I)/Cu(III) trifluoromethyl complexes with monophosphines. Dalton Trans., 2019, 48(3), 848-853.
[7] Chang Xiao, Hai-Xing Wan and Song-Lin Zhang*. Regio- and Stereoselective Vicinal syn-Arylation-trifluoromethylation of Terminal Arylacetylenes. Asian J. Org. Chem. 2019, 8(5), 654-657. Invited paper for a themed issue of “Organofluorine Chemistry”.
[8] Song-Lin Zhang*, Chang Xiao. Cu(III)-CF3 complex enabled unusual (Z)-selective hydro-trifluoromethylation of terminal alkynes. J. Org. Chem. 2018, 83(18), 10908-10915.
[9] Song-Lin Zhang*, Chang Xiao and Hai-Xing Wan. Diverse copper(III) trifluoromethyl complexes with mono-, bi- and tridentate ligands and their versatile reactivity. Dalton Trans., 2018, 47, 4779-4784.
[10] Song-Lin Zhang*, Hai-Xing Wan and Wen-Feng Bie, syn-Fluoro- and -Oxy-trifluoromethylation of Arylacetylenes. Org. Lett., 2017, 19(23), 6372-6375.
[11] Song-Lin Zhang*, Xian-Jin Wang and Ze-Long Yu. Chemoselective Access to γ-Ketoesters with Stereogenic Quaternary α-Center or γ-Keto Nitriles by Aerobic Reaction of α-Cyanoesters and Styrenes. Org. Lett. 2017, 19(12), 3139-3142.
[12] Song-Lin Zhang*, Hai-Xing Wan and Zhu-Qing Deng. A computational study on the mechanism of ynamide-mediated amide bond formation from carboxylic acids and amines. Org. Biomol. Chem. 2017, 15(30), 6367-6374.
[13] Xian-Jin Wang and Song-Lin Zhang*. Cyanation of aromatic/vinylic boronic acids with α-cyanoacetates. New J. Chem. 2017, 41(24), 14826-14830.
[14] Song-Lin Zhang* and Zhu-Qin Deng. Synthesis and reductive elimination of arylPd(II) trifluoromethyl complexes: a remarkable concentration effect on chemoselectivity. Phys. Chem. Chem. Phys. 2016, 18(48), 32664-32667.
[15] Song-Lin Zhang* and Wen-Feng Bie, Ligand-dependent formation of ion-pair CuI/CuIII trifluoromethyl complexes containing bisphosphines. Dalton Transactions 2016, 45(44), 17588-17592. ----期刊back cover论文
[16] Song-Lin Zhang* and Ze-Long Yu. C-C activation by retro-aldol reaction of two β-hydroxy carbonyl compounds: Synergy with Pd-catalyzed cross-coupling to access mono-α-arylated ketones and esters. J. Org. Chem. 2016, 81(1), 57-65. (IF: 4.849)
[17] Song-Lin Zhang* and Zhu-Qin Deng. Copper-catalyzed retro-aldol reaction of β-hydroxy ketones or nitriles with aldehydes: chemo- and stereoselective access to (E)-enones and (E)-acrylonitriles. Org. Biomol. Chem. 2016, 14, 7282-7294.
[18] Song-Lin Zhang* and Zhu-Qin Deng. Synthesis of quinolines and naphthyridines via catalytic retro-aldol reaction of β-hydroxyketones with ortho-aminobenzaldehydes or nicotinaldehydes. Org. Biomol. Chem. 2016, 14, 8966-8970.
[19] Song-Lin Zhang* and Ze-Long Yu. Divergent synthesis of indoles, oxindoles, isocoumarins and isoquinolinones by general Pd-catalyzed retro-aldol/α-arylation. Org. Biomol. Chem. 2016, 14, 10511-10515.
[20] Song-Lin Zhang* and Wen-Feng Bie. Isolation and characterization of copper(III) trifluoromethyl complexes and reactivity studies of aerobic trifluoromethylation of arylboronic acids. RSC Advances 2016, 6(75), 70902-70906.
[21] Song-Lin Zhang* and Lu Huang. Copper-catalyzed cyanation of aryl iodides with α-cyanoacetates via C–CN bond activation. Org. Biomol. Chem. 2015, 13(39), 9963-9968.—该期刊2015年第39期front cover论文.
[22] Song-Lin Zhang*, Lu Huang and Li-Jun Sun. The mechanism, electronic and ligand effects for reductive elimination from arylPd(II) trifluoromethyl complexes: a systematic DFT study. Dalton Trans. 2015, 44(10), 4613-4622.
[23] Song-Lin Zhang*, Wen-Feng Bie and Lu Huang. Theoretical Insights into Mechanisms for Copper(I)-Catalyzed C-P Coupling of Diarylphosphines with Aryl Halides: A Combined Solvent and Ancillary Ligand Effect on the Identity of Active Catalyst and Reaction Mechanism. Organometallics 2014, 33, 5263-5271.
[24] Song-Lin Zhang*, Lu Huang and Wen-Feng Bie. Mechanism for Activation of the C-CN Bond of Nitriles by a Cationic CpRhIII-Silyl Complex: A Systematic DFT Study. Organometallics 2014, 33, 3030-3039.
[25] Song-Lin Zhang* and Hui-Jun Fan. Theoretical Study on Copper-Catalyzed S-arylation of Thiophenols with Aryl Halides: Evidence Supporting the LCu(I)-SPh Active Catalyst and Halogen Atom Transfer Mechanism. Organometallics 2013, 32(17), 4944-4951.
[26] Liang Li, Feng Wu, Songlin Zhang*, Dawei Wang, Yuqiang Ding* and Zhenzhong Zhu. A heteroleptic cyclometalated iridium(III) fluorophenylpyridine complex from partial defluorohydrogenation reaction : synthesis, photophysical properties and mechanistic insights. Dalton Trans. 2013, 42, 4539.
[27] Songlin Zhang*, Zhenzhong Zhu and Yuqiang Ding, Proposal for Halogen Atom Transfer Mechanism for Ullmann O-arylation of Aryl Halides with Phenols. Dalton Trans. 2012, 41, 13832.
[28] Songlin Zhang*, Li Shi, Yuqiang Ding. Theoretical Analysis of the Mechanism of Pd(II) Acetate-Catalyzed Oxidative Heck Coupling of Electron-Deficient Arenes with Alkenes: Effects of the Pyridine-Type Ancillary Ligand and Origins of the meta-Regioselectivity. J. Am. Chem. Soc. 2011. 133, 20218.
[29] Song-Lin Zhang, Yao Fu*, Rui Shang, Qing-Xiang Guo, Lei Liu*.Theoretical Analysis of Factors Controlling Pd-Catalyzed Decarboxylative Coupling of Carboxylic Acids with Olefins. J. Am. Chem. Soc. 2010, 132, 638.
[30] Wei Yang, Songlin Zhang*, Yuqiang Ding*, Li Shi, Qijun Song. A Photoluminescent Dinuclear Phenylquinolyl Ir(II)-Ir(II) Complex Featuring a Phenylquinolyl Bridge and an End-on Dinitrogen Ligand. Chem. Commun. 2011, 47, 5310.
[31] Songlin Zhang, Yuqiang Ding*. Theoretical Study on Mechanism of Copper(I)-Catalyzed Cross-Coupling between Aryl Halides and Alkylamines. Organometallics 2011, 30, 633.
专利
1.中国发明专利：制备聚醚酰胺材料的方法. ZL201210270136.5. 授权日期：2013.12.25。
2.中国发明专利：具有吸湿和抗静电性能的聚醚胺改性尼龙材料的制备方法。ZL201310003523.7。授权日期：2014.09.03。
3.中国发明专利：胺基聚醚改性聚硅氧烷消泡剂的制备方法。ZL201310164057.0。授权日期：2015.8.12。
获 奖
1.2010年中国科学院院长优秀奖；
2.2015年江苏省科学技术奖三等奖；
3.2018年中国商业联合会科学技术奖三等奖；
4.2014-2017年江南大学“至善青年学者”荣誉称号
联 系 方 式
地址：新疆乌鲁木齐市农大东路311号8040威尼斯我院
邮编：830052
【以上信息更新至2020年10月】